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Charak Samhita

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त्रिरसानि यथासङ्ख्यं द्रव्याण्युक्तानि विंशतिः। वक्ष्यन्ते तु चतुष्केण द्रव्याणि दश पञ्च च ॥१७॥

Thereafter, the group of two-sweet and salt combining consecutively with pungent, bitter and astringent, form with the addition of sour, astringent and pungent respectively, three separate ‘group of fours’.

english translation